Which preposition to use with exudate

in Occurrences 1%

Under this unscientific, yet expressive term, is indicated a chronic diseased condition of the keratogenous membrane, commencing always at the frog, and slowly extending to the sole and wall, characterized by a loss of normal function of the horn secreting cells, and the discharge of a serous exudate in the place of normal horn.

Which preposition to use with  exudate